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Synergistic effect of nano-Pt and Ni spine for HER in alkaline solution: hydrogen spillover from nano-Pt to Ni spine

The design of active, stable, and cost-effective electrocatalysts for the H(2) evolution reaction (HER) in alkaline conditions is important for electrochemical systems such as the chloro-alkaline process and H(2) production. Here we report catalysts comprising Pt on Ni single crystalline spines (Pt/...

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Autores principales: Abbas, Syed Asad, Kim, Seong-Hoon, Iqbal, Muhammad Ibrahim, Muhammad, Shoaib, Yoon, Won-Sub, Jung, Kwang-Deog
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5813055/
https://www.ncbi.nlm.nih.gov/pubmed/29445208
http://dx.doi.org/10.1038/s41598-018-21396-9
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author Abbas, Syed Asad
Kim, Seong-Hoon
Iqbal, Muhammad Ibrahim
Muhammad, Shoaib
Yoon, Won-Sub
Jung, Kwang-Deog
author_facet Abbas, Syed Asad
Kim, Seong-Hoon
Iqbal, Muhammad Ibrahim
Muhammad, Shoaib
Yoon, Won-Sub
Jung, Kwang-Deog
author_sort Abbas, Syed Asad
collection PubMed
description The design of active, stable, and cost-effective electrocatalysts for the H(2) evolution reaction (HER) in alkaline conditions is important for electrochemical systems such as the chloro-alkaline process and H(2) production. Here we report catalysts comprising Pt on Ni single crystalline spines (Pt/Ni-SP) with high activity and stability for HER in alkaline solution with proposed mechanism. The Pt/Ni-SP catalysts are prepared by dispersing platinum nanoparticles (1.7–3.1 nm) on the single-crystalline spines (Ni-SP) of Ni urchin-like particles. The size and coverage of Pt nanoparticles on Ni-SP are increased with increases in the Pt loading amount. X-ray diffraction, high-resolution transmission electron microscopy, X-ray photoelectron spectroscopy, and X-ray absorption spectroscopy are performed to observe the structure of the Pt/Ni-SP catalyst. The catalysts achieve the mass activity of 1.11 A mg(−1)((Pt)), comparing favorably to Pt/C catalysts with the mass activity of 0.33 A mg(−1)((Pt)) at 0.05 V overpotential. The Tafel slope of the Pt/Ni-SP catalyst is approximately 30 mV dec(−1), similar to that of Pt, while Pt/Ni-SP is very stable in alkaline solution, like Ni. The synergistic effect of Pt/Ni-SP is ascribed to H spillover from Pt to Ni.
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spelling pubmed-58130552018-02-21 Synergistic effect of nano-Pt and Ni spine for HER in alkaline solution: hydrogen spillover from nano-Pt to Ni spine Abbas, Syed Asad Kim, Seong-Hoon Iqbal, Muhammad Ibrahim Muhammad, Shoaib Yoon, Won-Sub Jung, Kwang-Deog Sci Rep Article The design of active, stable, and cost-effective electrocatalysts for the H(2) evolution reaction (HER) in alkaline conditions is important for electrochemical systems such as the chloro-alkaline process and H(2) production. Here we report catalysts comprising Pt on Ni single crystalline spines (Pt/Ni-SP) with high activity and stability for HER in alkaline solution with proposed mechanism. The Pt/Ni-SP catalysts are prepared by dispersing platinum nanoparticles (1.7–3.1 nm) on the single-crystalline spines (Ni-SP) of Ni urchin-like particles. The size and coverage of Pt nanoparticles on Ni-SP are increased with increases in the Pt loading amount. X-ray diffraction, high-resolution transmission electron microscopy, X-ray photoelectron spectroscopy, and X-ray absorption spectroscopy are performed to observe the structure of the Pt/Ni-SP catalyst. The catalysts achieve the mass activity of 1.11 A mg(−1)((Pt)), comparing favorably to Pt/C catalysts with the mass activity of 0.33 A mg(−1)((Pt)) at 0.05 V overpotential. The Tafel slope of the Pt/Ni-SP catalyst is approximately 30 mV dec(−1), similar to that of Pt, while Pt/Ni-SP is very stable in alkaline solution, like Ni. The synergistic effect of Pt/Ni-SP is ascribed to H spillover from Pt to Ni. Nature Publishing Group UK 2018-02-14 /pmc/articles/PMC5813055/ /pubmed/29445208 http://dx.doi.org/10.1038/s41598-018-21396-9 Text en © The Author(s) 2018 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Article
Abbas, Syed Asad
Kim, Seong-Hoon
Iqbal, Muhammad Ibrahim
Muhammad, Shoaib
Yoon, Won-Sub
Jung, Kwang-Deog
Synergistic effect of nano-Pt and Ni spine for HER in alkaline solution: hydrogen spillover from nano-Pt to Ni spine
title Synergistic effect of nano-Pt and Ni spine for HER in alkaline solution: hydrogen spillover from nano-Pt to Ni spine
title_full Synergistic effect of nano-Pt and Ni spine for HER in alkaline solution: hydrogen spillover from nano-Pt to Ni spine
title_fullStr Synergistic effect of nano-Pt and Ni spine for HER in alkaline solution: hydrogen spillover from nano-Pt to Ni spine
title_full_unstemmed Synergistic effect of nano-Pt and Ni spine for HER in alkaline solution: hydrogen spillover from nano-Pt to Ni spine
title_short Synergistic effect of nano-Pt and Ni spine for HER in alkaline solution: hydrogen spillover from nano-Pt to Ni spine
title_sort synergistic effect of nano-pt and ni spine for her in alkaline solution: hydrogen spillover from nano-pt to ni spine
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5813055/
https://www.ncbi.nlm.nih.gov/pubmed/29445208
http://dx.doi.org/10.1038/s41598-018-21396-9
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