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Enantioselective Photochemical Organocascade Catalysis

Reported herein is a photochemical cascade process that combines the excited‐state and ground‐state reactivity of chiral organocatalytic intermediates. This strategy directly converts racemic cyclopropanols and α,β‐unsaturated aldehydes into stereochemically dense cyclopentanols with exquisite stere...

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Detalles Bibliográficos
Autores principales: Woźniak, Łukasz, Magagnano, Giandomenico, Melchiorre, Paolo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5814823/
https://www.ncbi.nlm.nih.gov/pubmed/29205718
http://dx.doi.org/10.1002/anie.201711397