Functionalization of N-arylglycine esters: electrocatalytic access to C–C bonds mediated by n-Bu(4)NI

An efficient electrocatalytic functionalization of N-arylglycine esters is reported. The protocol proceeds in an undivided cell under constant current conditions employing the simple, cheap and readily available n-Bu(4)NI as the mediator. In addition, it is demonstrated that the mediated process is...

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Detalles Bibliográficos
Autores principales: Luo, Mi-Hai, Jiang, Yang-Ye, Xu, Kun, Liu, Yong-Guo, Sun, Bao-Guo, Zeng, Cheng-Chu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2018
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5827798/
https://www.ncbi.nlm.nih.gov/pubmed/29520311
http://dx.doi.org/10.3762/bjoc.14.35
Descripción
Sumario:An efficient electrocatalytic functionalization of N-arylglycine esters is reported. The protocol proceeds in an undivided cell under constant current conditions employing the simple, cheap and readily available n-Bu(4)NI as the mediator. In addition, it is demonstrated that the mediated process is superior to the direct electrochemical functionalization.

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