Functionalization of N-arylglycine esters: electrocatalytic access to C–C bonds mediated by n-Bu(4)NI

An efficient electrocatalytic functionalization of N-arylglycine esters is reported. The protocol proceeds in an undivided cell under constant current conditions employing the simple, cheap and readily available n-Bu(4)NI as the mediator. In addition, it is demonstrated that the mediated process is...

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Detalles Bibliográficos
Autores principales: Luo, Mi-Hai, Jiang, Yang-Ye, Xu, Kun, Liu, Yong-Guo, Sun, Bao-Guo, Zeng, Cheng-Chu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2018
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5827798/
https://www.ncbi.nlm.nih.gov/pubmed/29520311
http://dx.doi.org/10.3762/bjoc.14.35
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author Luo, Mi-Hai
Jiang, Yang-Ye
Xu, Kun
Liu, Yong-Guo
Sun, Bao-Guo
Zeng, Cheng-Chu
author_facet Luo, Mi-Hai
Jiang, Yang-Ye
Xu, Kun
Liu, Yong-Guo
Sun, Bao-Guo
Zeng, Cheng-Chu
author_sort Luo, Mi-Hai
collection PubMed
description An efficient electrocatalytic functionalization of N-arylglycine esters is reported. The protocol proceeds in an undivided cell under constant current conditions employing the simple, cheap and readily available n-Bu(4)NI as the mediator. In addition, it is demonstrated that the mediated process is superior to the direct electrochemical functionalization.
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spelling pubmed-58277982018-03-08 Functionalization of N-arylglycine esters: electrocatalytic access to C–C bonds mediated by n-Bu(4)NI Luo, Mi-Hai Jiang, Yang-Ye Xu, Kun Liu, Yong-Guo Sun, Bao-Guo Zeng, Cheng-Chu Beilstein J Org Chem Full Research Paper An efficient electrocatalytic functionalization of N-arylglycine esters is reported. The protocol proceeds in an undivided cell under constant current conditions employing the simple, cheap and readily available n-Bu(4)NI as the mediator. In addition, it is demonstrated that the mediated process is superior to the direct electrochemical functionalization. Beilstein-Institut 2018-02-22 /pmc/articles/PMC5827798/ /pubmed/29520311 http://dx.doi.org/10.3762/bjoc.14.35 Text en Copyright © 2018, Luo et al. https://creativecommons.org/licenses/by/4.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Luo, Mi-Hai
Jiang, Yang-Ye
Xu, Kun
Liu, Yong-Guo
Sun, Bao-Guo
Zeng, Cheng-Chu
Functionalization of N-arylglycine esters: electrocatalytic access to C–C bonds mediated by n-Bu(4)NI
title Functionalization of N-arylglycine esters: electrocatalytic access to C–C bonds mediated by n-Bu(4)NI
title_full Functionalization of N-arylglycine esters: electrocatalytic access to C–C bonds mediated by n-Bu(4)NI
title_fullStr Functionalization of N-arylglycine esters: electrocatalytic access to C–C bonds mediated by n-Bu(4)NI
title_full_unstemmed Functionalization of N-arylglycine esters: electrocatalytic access to C–C bonds mediated by n-Bu(4)NI
title_short Functionalization of N-arylglycine esters: electrocatalytic access to C–C bonds mediated by n-Bu(4)NI
title_sort functionalization of n-arylglycine esters: electrocatalytic access to c–c bonds mediated by n-bu(4)ni
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5827798/
https://www.ncbi.nlm.nih.gov/pubmed/29520311
http://dx.doi.org/10.3762/bjoc.14.35
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