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Dual properties of a hydrogen oxidation Ni-catalyst entrapped within a polymer promote self-defense against oxygen

The Ni(P(2)N(2))(2) catalysts are among the most efficient non-noble-metal based molecular catalysts for H(2) cycling. However, these catalysts are O(2) sensitive and lack long term stability under operating conditions. Here, we show that in a redox silent polymer matrix the catalyst is dispersed in...

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Detalles Bibliográficos
Autores principales: Oughli, Alaa A., Ruff, Adrian, Boralugodage, Nilusha Priyadarshani, Rodríguez-Maciá, Patricia, Plumeré, Nicolas, Lubitz, Wolfgang, Shaw, Wendy J., Schuhmann, Wolfgang, Rüdiger, Olaf
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5830441/
https://www.ncbi.nlm.nih.gov/pubmed/29491416
http://dx.doi.org/10.1038/s41467-018-03011-7

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