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Dual properties of a hydrogen oxidation Ni-catalyst entrapped within a polymer promote self-defense against oxygen
The Ni(P(2)N(2))(2) catalysts are among the most efficient non-noble-metal based molecular catalysts for H(2) cycling. However, these catalysts are O(2) sensitive and lack long term stability under operating conditions. Here, we show that in a redox silent polymer matrix the catalyst is dispersed in...
Autores principales: | Oughli, Alaa A., Ruff, Adrian, Boralugodage, Nilusha Priyadarshani, Rodríguez-Maciá, Patricia, Plumeré, Nicolas, Lubitz, Wolfgang, Shaw, Wendy J., Schuhmann, Wolfgang, Rüdiger, Olaf |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5830441/ https://www.ncbi.nlm.nih.gov/pubmed/29491416 http://dx.doi.org/10.1038/s41467-018-03011-7 |
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