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Catalyst accessibility to chemical reductants in metal–organic frameworks

A molecular H(2)-evolving catalyst, [Fe(2)(cbdt)(CO)(6)] ([FeFe], cbdt = 3-carboxybenzene-1,2-dithiolate), has been attached covalently to an amino-functionalized MIL-101(Cr) through an amide bond. Chemical reduction experiments reveal that the MOF channels can be clogged by ion pairs that are forme...

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Detalles Bibliográficos
Autores principales:	Roy, Souvik, Pascanu, Vlad, Pullen, Sonja, González Miera, Greco, Martín-Matute, Belén, Ott, Sascha
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2017
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5836565/ https://www.ncbi.nlm.nih.gov/pubmed/28261731 http://dx.doi.org/10.1039/c7cc00022g

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