Monosulfonicpillar[5]arene: Synthesis, Characterization, and Complexation with Tetraphenylethene for Aggregation-Induced Emission

A pillar[5]arene derivative with a hydrophilic sulfonic group, i.e., monosulfonicpillar[5]arene (MSP5), has been successfully synthesized for the first time, which exhibited strong binding affinity towards alcohol analogs. Significantly, fluorescent supramolecular ensemble was fabricated from the su...

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Autores principales: Jin, Xiao-Yu, Song, Nan, Wang, Xu, Wang, Chun-Yu, Wang, Yan, Yang, Ying-Wei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5838235/
https://www.ncbi.nlm.nih.gov/pubmed/29507324
http://dx.doi.org/10.1038/s41598-018-22446-y
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author Jin, Xiao-Yu
Song, Nan
Wang, Xu
Wang, Chun-Yu
Wang, Yan
Yang, Ying-Wei
author_facet Jin, Xiao-Yu
Song, Nan
Wang, Xu
Wang, Chun-Yu
Wang, Yan
Yang, Ying-Wei
author_sort Jin, Xiao-Yu
collection PubMed
description A pillar[5]arene derivative with a hydrophilic sulfonic group, i.e., monosulfonicpillar[5]arene (MSP5), has been successfully synthesized for the first time, which exhibited strong binding affinity towards alcohol analogs. Significantly, fluorescent supramolecular ensemble was fabricated from the supramolecular complexation of MSP5 and a neutral guest with tetraphenylethene core. Enhanced fluorescent emission of this system can be detected both in dilute solution and the solid state, and its temperature and competitive guest multi-responsive properties suggest its promising application as a chemical sensor towards alcohol analogs, ethylenediamine, and temperature variations.
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spelling pubmed-58382352018-03-12 Monosulfonicpillar[5]arene: Synthesis, Characterization, and Complexation with Tetraphenylethene for Aggregation-Induced Emission Jin, Xiao-Yu Song, Nan Wang, Xu Wang, Chun-Yu Wang, Yan Yang, Ying-Wei Sci Rep Article A pillar[5]arene derivative with a hydrophilic sulfonic group, i.e., monosulfonicpillar[5]arene (MSP5), has been successfully synthesized for the first time, which exhibited strong binding affinity towards alcohol analogs. Significantly, fluorescent supramolecular ensemble was fabricated from the supramolecular complexation of MSP5 and a neutral guest with tetraphenylethene core. Enhanced fluorescent emission of this system can be detected both in dilute solution and the solid state, and its temperature and competitive guest multi-responsive properties suggest its promising application as a chemical sensor towards alcohol analogs, ethylenediamine, and temperature variations. Nature Publishing Group UK 2018-03-05 /pmc/articles/PMC5838235/ /pubmed/29507324 http://dx.doi.org/10.1038/s41598-018-22446-y Text en © The Author(s) 2018 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Article
Jin, Xiao-Yu
Song, Nan
Wang, Xu
Wang, Chun-Yu
Wang, Yan
Yang, Ying-Wei
Monosulfonicpillar[5]arene: Synthesis, Characterization, and Complexation with Tetraphenylethene for Aggregation-Induced Emission
title Monosulfonicpillar[5]arene: Synthesis, Characterization, and Complexation with Tetraphenylethene for Aggregation-Induced Emission
title_full Monosulfonicpillar[5]arene: Synthesis, Characterization, and Complexation with Tetraphenylethene for Aggregation-Induced Emission
title_fullStr Monosulfonicpillar[5]arene: Synthesis, Characterization, and Complexation with Tetraphenylethene for Aggregation-Induced Emission
title_full_unstemmed Monosulfonicpillar[5]arene: Synthesis, Characterization, and Complexation with Tetraphenylethene for Aggregation-Induced Emission
title_short Monosulfonicpillar[5]arene: Synthesis, Characterization, and Complexation with Tetraphenylethene for Aggregation-Induced Emission
title_sort monosulfonicpillar[5]arene: synthesis, characterization, and complexation with tetraphenylethene for aggregation-induced emission
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5838235/
https://www.ncbi.nlm.nih.gov/pubmed/29507324
http://dx.doi.org/10.1038/s41598-018-22446-y
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