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Synthesis and Properties of Open Fullerenes Encapsulating Ammonia and Methane

We describe the synthesis and characterisation of open fullerene (1) and its reduced form (2) in which CH(4) and NH(3) are encapsulated, respectively. The (1)H NMR resonance of endohedral NH(3) is broadened by scalar coupling to the quadrupolar (14) n nucleus, which relaxes rapidly. This broadening...

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Detalles Bibliográficos
Autores principales: Bloodworth, Sally, Gräsvik, John, Alom, Shamim, Kouřil, Karel, Elliott, Stuart J., Wells, Neil J., Horsewill, Anthony J., Mamone, Salvatore, Jiménez‐Ruiz, Mónica, Rols, Stéphane, Nagel, Urmas, Rõõm, Toomas, Levitt, Malcolm H., Whitby, Richard J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5838534/
https://www.ncbi.nlm.nih.gov/pubmed/29131544
http://dx.doi.org/10.1002/cphc.201701212