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Synthesis and Properties of Open Fullerenes Encapsulating Ammonia and Methane
We describe the synthesis and characterisation of open fullerene (1) and its reduced form (2) in which CH(4) and NH(3) are encapsulated, respectively. The (1)H NMR resonance of endohedral NH(3) is broadened by scalar coupling to the quadrupolar (14) n nucleus, which relaxes rapidly. This broadening...
Autores principales: | , , , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5838534/ https://www.ncbi.nlm.nih.gov/pubmed/29131544 http://dx.doi.org/10.1002/cphc.201701212 |