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Synthesis of α‐Chiral Ketones and Chiral Alkanes Using Radical Polar Crossover Reactions of Vinyl Boron Ate Complexes

Vinyl boron ate complexes of enantioenriched secondary alkyl pinacolboronic esters undergo stereospecific radical‐induced 1,2‐migration in radical polar crossover reactions. In this three‐component process various commercially available alkyl iodides act as radical precursors and light is used for c...

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Detalles Bibliográficos
Autores principales:	Gerleve, Carolin, Kischkewitz, Marvin, Studer, Armido
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2018
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5838550/ https://www.ncbi.nlm.nih.gov/pubmed/29239507 http://dx.doi.org/10.1002/anie.201711390

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