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Broad-Scope Rh-Catalyzed Inverse-Sonogashira Reaction Directed by Weakly Coordinating Groups

[Image: see text] We report the alkynylation of C(sp(2))–H bonds with bromoalkynes (inverse-Sonogashira reaction) directed by synthetically useful ester, ketone, and ether groups under rhodium catalysis. Other less common directing groups such as amine, thioether, sulfoxide, sulfone, phenol ester, a...

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Detalles Bibliográficos
Autores principales: Tan, Eric, Quinonero, Ophélie, Elena de Orbe, M., Echavarren, Antonio M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5838643/
https://www.ncbi.nlm.nih.gov/pubmed/29527402
http://dx.doi.org/10.1021/acscatal.7b04395