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Exploring the Formation of Black Phosphorus Intercalation Compounds with Alkali Metals
Black phosphorus intercalation compounds (BPICs) with alkali metals (namely: K and Na) have been synthesized in bulk by solid‐state as well as vapor‐phase reactions. By means of a combination of in situ X‐ray diffraction, Raman spectroscopy, and DFT calculations the structural behavior of the BPICs...
| Autores principales: | , , , , , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5846882/ https://www.ncbi.nlm.nih.gov/pubmed/28980764 http://dx.doi.org/10.1002/anie.201707462 |
| _version_ | 1783305650428706816 |
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| author | Abellán, Gonzalo Neiss, Christian Lloret, Vicent Wild, Stefan Chacón‐Torres, Julio C. Werbach, Katharina Fedi, Filippo Shiozawa, Hidetsugu Görling, Andreas Peterlik, Herwig Pichler, Thomas Hauke, Frank Hirsch, Andreas |
| author_facet | Abellán, Gonzalo Neiss, Christian Lloret, Vicent Wild, Stefan Chacón‐Torres, Julio C. Werbach, Katharina Fedi, Filippo Shiozawa, Hidetsugu Görling, Andreas Peterlik, Herwig Pichler, Thomas Hauke, Frank Hirsch, Andreas |
| author_sort | Abellán, Gonzalo |
| collection | PubMed |
| description | Black phosphorus intercalation compounds (BPICs) with alkali metals (namely: K and Na) have been synthesized in bulk by solid‐state as well as vapor‐phase reactions. By means of a combination of in situ X‐ray diffraction, Raman spectroscopy, and DFT calculations the structural behavior of the BPICs at different intercalation stages has been demonstrated for the first time. Our results provide a glimpse into the very first steps of a new family of intercalation compounds, with a distinct behavior as compared to its graphite analogues (GICs), showing a remarkable structural complexity and a dynamic behavior. |
| format | Online Article Text |
| id | pubmed-5846882 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2017 |
| publisher | John Wiley and Sons Inc. |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-58468822018-03-20 Exploring the Formation of Black Phosphorus Intercalation Compounds with Alkali Metals Abellán, Gonzalo Neiss, Christian Lloret, Vicent Wild, Stefan Chacón‐Torres, Julio C. Werbach, Katharina Fedi, Filippo Shiozawa, Hidetsugu Görling, Andreas Peterlik, Herwig Pichler, Thomas Hauke, Frank Hirsch, Andreas Angew Chem Int Ed Engl Communications Black phosphorus intercalation compounds (BPICs) with alkali metals (namely: K and Na) have been synthesized in bulk by solid‐state as well as vapor‐phase reactions. By means of a combination of in situ X‐ray diffraction, Raman spectroscopy, and DFT calculations the structural behavior of the BPICs at different intercalation stages has been demonstrated for the first time. Our results provide a glimpse into the very first steps of a new family of intercalation compounds, with a distinct behavior as compared to its graphite analogues (GICs), showing a remarkable structural complexity and a dynamic behavior. John Wiley and Sons Inc. 2017-10-26 2017-11-27 /pmc/articles/PMC5846882/ /pubmed/28980764 http://dx.doi.org/10.1002/anie.201707462 Text en © 2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial‐NoDerivs (http://creativecommons.org/licenses/by-nc-nd/4.0/) License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made. |
| spellingShingle | Communications Abellán, Gonzalo Neiss, Christian Lloret, Vicent Wild, Stefan Chacón‐Torres, Julio C. Werbach, Katharina Fedi, Filippo Shiozawa, Hidetsugu Görling, Andreas Peterlik, Herwig Pichler, Thomas Hauke, Frank Hirsch, Andreas Exploring the Formation of Black Phosphorus Intercalation Compounds with Alkali Metals |
| title | Exploring the Formation of Black Phosphorus Intercalation Compounds with Alkali Metals |
| title_full | Exploring the Formation of Black Phosphorus Intercalation Compounds with Alkali Metals |
| title_fullStr | Exploring the Formation of Black Phosphorus Intercalation Compounds with Alkali Metals |
| title_full_unstemmed | Exploring the Formation of Black Phosphorus Intercalation Compounds with Alkali Metals |
| title_short | Exploring the Formation of Black Phosphorus Intercalation Compounds with Alkali Metals |
| title_sort | exploring the formation of black phosphorus intercalation compounds with alkali metals |
| topic | Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5846882/ https://www.ncbi.nlm.nih.gov/pubmed/28980764 http://dx.doi.org/10.1002/anie.201707462 |
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