Formylation or methylation: what determines the chemoselectivity of the reaction of amine, CO(2), and hydrosilane catalyzed by 1,3,2-diazaphospholene?

DFT computations have been performed to gain insight into the mechanisms of formylation/methylation of amines (e.g. methylaniline (1a)/2,2,4,4-tetramethylpiperidine (2a)) with CO(2) and hydrosilane ([Si]H(2), [Si] = Ph(2)Si), catalyzed by 1,3,2-diazaphospholene ([NHP]H). Different from the generally...

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Detalles Bibliográficos
Autores principales: Lu, Yu, Gao, Zhong-Hua, Chen, Xiang-Yu, Guo, Jiandong, Liu, Zheyuan, Dang, Yanfeng, Ye, Song, Wang, Zhi-Xiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5849201/
https://www.ncbi.nlm.nih.gov/pubmed/29568428
http://dx.doi.org/10.1039/c7sc00824d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5849201/
https://www.ncbi.nlm.nih.gov/pubmed/29568428
http://dx.doi.org/10.1039/c7sc00824d

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