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Formylation or methylation: what determines the chemoselectivity of the reaction of amine, CO(2), and hydrosilane catalyzed by 1,3,2-diazaphospholene?
DFT computations have been performed to gain insight into the mechanisms of formylation/methylation of amines (e.g. methylaniline (1a)/2,2,4,4-tetramethylpiperidine (2a)) with CO(2) and hydrosilane ([Si]H(2), [Si] = Ph(2)Si), catalyzed by 1,3,2-diazaphospholene ([NHP]H). Different from the generally...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5849201/ https://www.ncbi.nlm.nih.gov/pubmed/29568428 http://dx.doi.org/10.1039/c7sc00824d |