Template-directed self-assembly of dynamic covalent capsules with polar interiors

Chiral polyimine molecular capsules with polar interiors have been prepared through template covalent dynamic self-assembly. An aryl-extended tetraaldehyde calix[4]pyrrole scaffold was condensed with suitable diamines as linkers using templates for efficient self-assembly. The capsular complexes wer...

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Detalles Bibliográficos
Autores principales: Galán, Albano, Escudero-Adán, Eduardo C., Ballester, Pablo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5853267/
https://www.ncbi.nlm.nih.gov/pubmed/29568438
http://dx.doi.org/10.1039/c7sc03731g
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author Galán, Albano
Escudero-Adán, Eduardo C.
Ballester, Pablo
author_facet Galán, Albano
Escudero-Adán, Eduardo C.
Ballester, Pablo
author_sort Galán, Albano
collection PubMed
description Chiral polyimine molecular capsules with polar interiors have been prepared through template covalent dynamic self-assembly. An aryl-extended tetraaldehyde calix[4]pyrrole scaffold was condensed with suitable diamines as linkers using templates for efficient self-assembly. The capsular complexes were characterized in solution, gas phase and the solid-state. Unprecedented transfer of asymmetry was observed from a chiral diamine linker to the resulting supramolecular capsular assembly.
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spelling pubmed-58532672018-03-22 Template-directed self-assembly of dynamic covalent capsules with polar interiors Galán, Albano Escudero-Adán, Eduardo C. Ballester, Pablo Chem Sci Chemistry Chiral polyimine molecular capsules with polar interiors have been prepared through template covalent dynamic self-assembly. An aryl-extended tetraaldehyde calix[4]pyrrole scaffold was condensed with suitable diamines as linkers using templates for efficient self-assembly. The capsular complexes were characterized in solution, gas phase and the solid-state. Unprecedented transfer of asymmetry was observed from a chiral diamine linker to the resulting supramolecular capsular assembly. Royal Society of Chemistry 2017-11-01 2017-09-26 /pmc/articles/PMC5853267/ /pubmed/29568438 http://dx.doi.org/10.1039/c7sc03731g Text en This journal is © The Royal Society of Chemistry 2017 http://creativecommons.org/licenses/by/3.0/ This article is freely available. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (CC BY 3.0)
spellingShingle Chemistry
Galán, Albano
Escudero-Adán, Eduardo C.
Ballester, Pablo
Template-directed self-assembly of dynamic covalent capsules with polar interiors
title Template-directed self-assembly of dynamic covalent capsules with polar interiors
title_full Template-directed self-assembly of dynamic covalent capsules with polar interiors
title_fullStr Template-directed self-assembly of dynamic covalent capsules with polar interiors
title_full_unstemmed Template-directed self-assembly of dynamic covalent capsules with polar interiors
title_short Template-directed self-assembly of dynamic covalent capsules with polar interiors
title_sort template-directed self-assembly of dynamic covalent capsules with polar interiors
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5853267/
https://www.ncbi.nlm.nih.gov/pubmed/29568438
http://dx.doi.org/10.1039/c7sc03731g
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