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Bond breakage under pressure in a metal organic framework

The internal free volume of porous materials diminishes upon mechanical compression, and such volume collapse can have chemical consequences. We report here the endothermic bond breakage in a metal-organic framework (MOF) during compression-induced collapse. Upon bulk compression at 1.9 GPa, the eff...

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Detalles Bibliográficos
Autores principales:	Su, Zhi, Miao, Yu-Run, Zhang, Guanghui, Miller, Jeffrey T., Suslick, Kenneth S.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2017
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5853553/ https://www.ncbi.nlm.nih.gov/pubmed/29568447 http://dx.doi.org/10.1039/c7sc03786d

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