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Synthesis and Electrochemical Properties of Two-Dimensional RGO/Ti(3)C(2)T(x) Nanocomposites

MXene is a new type of two-dimensional layered material. Herein, a GO/Ti(3)C(2)T(x) nanocomposite was prepared by a simple liquid phase method, and the obtained GO/Ti(3)C(2)T(x) was transformed into RGO/Ti(3)C(2)T(x) under high temperature with Ar/H(2.) The prepared samples were characterized using...

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Autores principales: Shen, Changjie, Wang, Libo, Zhou, Aiguo, Wang, Bo, Wang, Xiaolong, Lian, Weiwei, Hu, Qianku, Qin, Gang, Liu, Xuqing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5853712/
https://www.ncbi.nlm.nih.gov/pubmed/29385083
http://dx.doi.org/10.3390/nano8020080
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author Shen, Changjie
Wang, Libo
Zhou, Aiguo
Wang, Bo
Wang, Xiaolong
Lian, Weiwei
Hu, Qianku
Qin, Gang
Liu, Xuqing
author_facet Shen, Changjie
Wang, Libo
Zhou, Aiguo
Wang, Bo
Wang, Xiaolong
Lian, Weiwei
Hu, Qianku
Qin, Gang
Liu, Xuqing
author_sort Shen, Changjie
collection PubMed
description MXene is a new type of two-dimensional layered material. Herein, a GO/Ti(3)C(2)T(x) nanocomposite was prepared by a simple liquid phase method, and the obtained GO/Ti(3)C(2)T(x) was transformed into RGO/Ti(3)C(2)T(x) under high temperature with Ar/H(2.) The prepared samples were characterized using X-ray diffraction (XRD), Raman measurement, scanning electron microscopy (SEM), energy disperse spectroscopy (EDS), and X-ray photoelectron spectroscopy (XPS). As an electrode material in lithium-ion batteries, the RGO/Ti(3)C(2)T(x) nanocomposite exhibited an excellent electrochemical performance and an excellent rate performance. Compared to pure Ti(3)C(2)T(x), the nanocomposite had a better reversible capacity at different current densities and had no attenuation after 200 cycles, which is one time higher than pure Ti(3)C(2)T(x). The improvement in the specific capacity was due to the excellent electrical conductivity and the unique structure of RGO, in which a charge transfer bridge was built among the Ti(3)C(2)T(x) flakes. Such a bridge shortened the transmission distance of the electrons and ions and effectively controlled the restacking of the laminated materials.
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spelling pubmed-58537122018-03-16 Synthesis and Electrochemical Properties of Two-Dimensional RGO/Ti(3)C(2)T(x) Nanocomposites Shen, Changjie Wang, Libo Zhou, Aiguo Wang, Bo Wang, Xiaolong Lian, Weiwei Hu, Qianku Qin, Gang Liu, Xuqing Nanomaterials (Basel) Article MXene is a new type of two-dimensional layered material. Herein, a GO/Ti(3)C(2)T(x) nanocomposite was prepared by a simple liquid phase method, and the obtained GO/Ti(3)C(2)T(x) was transformed into RGO/Ti(3)C(2)T(x) under high temperature with Ar/H(2.) The prepared samples were characterized using X-ray diffraction (XRD), Raman measurement, scanning electron microscopy (SEM), energy disperse spectroscopy (EDS), and X-ray photoelectron spectroscopy (XPS). As an electrode material in lithium-ion batteries, the RGO/Ti(3)C(2)T(x) nanocomposite exhibited an excellent electrochemical performance and an excellent rate performance. Compared to pure Ti(3)C(2)T(x), the nanocomposite had a better reversible capacity at different current densities and had no attenuation after 200 cycles, which is one time higher than pure Ti(3)C(2)T(x). The improvement in the specific capacity was due to the excellent electrical conductivity and the unique structure of RGO, in which a charge transfer bridge was built among the Ti(3)C(2)T(x) flakes. Such a bridge shortened the transmission distance of the electrons and ions and effectively controlled the restacking of the laminated materials. MDPI 2018-01-31 /pmc/articles/PMC5853712/ /pubmed/29385083 http://dx.doi.org/10.3390/nano8020080 Text en © 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Shen, Changjie
Wang, Libo
Zhou, Aiguo
Wang, Bo
Wang, Xiaolong
Lian, Weiwei
Hu, Qianku
Qin, Gang
Liu, Xuqing
Synthesis and Electrochemical Properties of Two-Dimensional RGO/Ti(3)C(2)T(x) Nanocomposites
title Synthesis and Electrochemical Properties of Two-Dimensional RGO/Ti(3)C(2)T(x) Nanocomposites
title_full Synthesis and Electrochemical Properties of Two-Dimensional RGO/Ti(3)C(2)T(x) Nanocomposites
title_fullStr Synthesis and Electrochemical Properties of Two-Dimensional RGO/Ti(3)C(2)T(x) Nanocomposites
title_full_unstemmed Synthesis and Electrochemical Properties of Two-Dimensional RGO/Ti(3)C(2)T(x) Nanocomposites
title_short Synthesis and Electrochemical Properties of Two-Dimensional RGO/Ti(3)C(2)T(x) Nanocomposites
title_sort synthesis and electrochemical properties of two-dimensional rgo/ti(3)c(2)t(x) nanocomposites
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5853712/
https://www.ncbi.nlm.nih.gov/pubmed/29385083
http://dx.doi.org/10.3390/nano8020080
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