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Ex situ generation of stoichiometric HCN and its application in the Pd-catalysed cyanation of aryl bromides: evidence for a transmetallation step between two oxidative addition Pd-complexes
A protocol for the Pd-catalysed cyanation of aryl bromides using near stoichiometric and gaseous hydrogen cyanide is reported for the first time. A two-chamber reactor was adopted for the safe liberation of ex situ generated HCN in a closed environment, which proved highly efficient in the Ni-cataly...
Autores principales: | Kristensen, Steffan K., Eikeland, Espen Z., Taarning, Esben, Lindhardt, Anders T., Skrydstrup, Troels |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5855124/ https://www.ncbi.nlm.nih.gov/pubmed/29568458 http://dx.doi.org/10.1039/c7sc03912c |
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