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Catalysis with chalcogen bonds: neutral benzodiselenazole scaffolds with high-precision selenium donors of variable strength
The benzodiselenazoles (BDS) introduced in this report fulfill, for the first time, all the prerequisites for non-covalent high-precision chalcogen-bonding catalysis in the focal point of conformationally immobilized σ holes on strong selenium donors in a neutral scaffold. Rational bite-angle adjust...
Autores principales: | Benz, Sebastian, Mareda, Jiri, Besnard, Céline, Sakai, Naomi, Matile, Stefan |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5855965/ https://www.ncbi.nlm.nih.gov/pubmed/29568463 http://dx.doi.org/10.1039/c7sc03866f |
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