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Site-isolated manganese carbonyl on bipyridine-functionalities of periodic mesoporous organosilicas: efficient CO(2) photoreduction and detection of key reaction intermediates

Well-defined and fully characterized supported CO(2) reduction catalysts are developed through the immobilization of an earth abundant Mn complex on bpy-PMO (bpy = bipyridine; PMO = Periodic Mesoporous Organosilica) platform materials. The resulting isolated Mn-carbonyl centers coordinated to bipyri...

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Detalles Bibliográficos
Autores principales:	Wang, Xia, Thiel, Indre, Fedorov, Alexey, Copéret, Christophe, Mougel, Victor, Fontecave, Marc
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2017
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5857931/ https://www.ncbi.nlm.nih.gov/pubmed/29568468 http://dx.doi.org/10.1039/c7sc03512h

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