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Direct structural identification of carbenium ions and investigation of host–guest interaction in the methanol to olefins reaction obtained by multinuclear NMR correlations

Probing and determining the intermediates formed during catalytic reactions in heterogeneous catalysis are strong challenges. Using (13)C labelling and two dimensional (13)C–(13)C through-bond NMR correlations, we directly reveal the structures of a range of carbenium ion species formed during the c...

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Detalles Bibliográficos
Autores principales: Xiao, Dong, Xu, Shutao, Han, Xiuwen, Bao, Xinhe, Liu, Zhongmin, Blanc, Frédéric
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5858018/
https://www.ncbi.nlm.nih.gov/pubmed/29619177
http://dx.doi.org/10.1039/c7sc03657d