Cargando…

Unveiling the role of boroxines in metal-free carbon–carbon homologations using diazo compounds and boronic acids

By means of computational and experimental mechanistic studies the fundamental role of boroxines in the reaction between diazo compounds and boronic acids was elucidated. Consequently, a selective metal-free carbon–carbon homologation of aryl and vinyl boroxines using TMSCHN(2), giving access to TMS...

Descripción completa

Detalles Bibliográficos
Autores principales:	Bomio, Claudio, Kabeshov, Mikhail A., Lit, Arthur R., Lau, Shing-Hing, Ehlert, Janna, Battilocchio, Claudio, Ley, Steven V.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2017
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5859889/ https://www.ncbi.nlm.nih.gov/pubmed/29619197 http://dx.doi.org/10.1039/c7sc02264f

Ejemplares similares

Visible Light Activation of Boronic Esters Enables Efficient Photoredox C(sp(2))–C(sp(3)) Cross‐Couplings in Flow
por: Lima, Fabio, et al.
Publicado: (2016)

Conformational control enables boroxine-to-boronate cage metamorphosis
por: Rondelli, Manuel, et al.
Publicado: (2023)

Flow chemistry as a discovery tool to access sp(2)–sp(3) cross-coupling reactions via diazo compounds
por: Tran, Duc N., et al.
Publicado: (2015)

A Versatile Room-Temperature Route to Di- and Trisubstituted Allenes Using Flow-Generated Diazo Compounds**
por: Poh, Jian-Siang, et al.
Publicado: (2015)

Rapid Asymmetric Synthesis of Disubstituted Allenes by Coupling of Flow‐Generated Diazo Compounds and Propargylated Amines
por: Poh, Jian‐Siang, et al.
Publicado: (2017)

A Versatile Route to Unstable Diazo Compounds via Oxadiazolines and their Use in Aryl–Alkyl Cross‐Coupling Reactions
por: Greb, Andreas, et al.
Publicado: (2017)

In silico prediction suggests inhibitory effect of halogenated boroxine on human catalase and carbonic anhydrase
por: Corbo, Tarik, et al.
Publicado: (2022)

A multicomponent approach for the preparation of homoallylic alcohols
por: Poh, Jian-Siang, et al.
Publicado: (2016)

Novel Discotic Boroxines: Synthesis and Mesomorphic Properties
por: Wöhrle, Tobias, et al.
Publicado: (2014)

Boroxine benzaldehyde complex for pharmaceutical applications probed by electron interactions
por: Pereira‐da‐Silva, Joao, et al.
Publicado: (2022)

Z-Selective iridium-catalyzed cross-coupling of allylic carbonates and α-diazo esters
por: Thomas, Bryce N., et al.
Publicado: (2017)

Electronic properties of the boroxine–gold interface: evidence of ultra-fast charge delocalization
por: Toffoli, Daniele, et al.
Publicado: (2017)

Computational NEXAFS Characterization of Molecular Model Systems for 2D Boroxine Frameworks
por: Toffoli, Daniele, et al.
Publicado: (2022)

α-Diazo-λ(3)-iodanes and α-diazo sulfonium salts: the umpolung of diazo compounds
por: Timmann, Sven, et al.
Publicado: (2023)

Enabling Technologies for the Future of Chemical Synthesis
por: Fitzpatrick, Daniel E., et al.
Publicado: (2016)

Hybrid Boron-Carbon Chemistry
por: Oliva-Enrich, Josep M., et al.
Publicado: (2020)

Achieving Boron–Carbon–Nitrogen Heterostructures by Collision Fusion of Carbon Nanotubes and Boron Nitride Nanotubes
por: Zhang, Chao, et al.
Publicado: (2023)

Advantages of an Electrochemical Method Compared to the Spectrophotometric Kinetic Study of Peroxidase Inhibition by Boroxine Derivative
por: Ostojić, Jelena, et al.
Publicado: (2017)

In silico rationalisation of selectivity and reactivity in Pd-catalysed C–H activation reactions
por: Cao, Liwei, et al.
Publicado: (2020)

Detection of urinary microRNA biomarkers using diazo sulfonamide-modified screen printed carbon electrodes
por: Smith, Daniel A., et al.
Publicado: (2021)

Boron-Filled Hybrid Carbon Nanotubes
por: Patel, Rajen B., et al.
Publicado: (2016)

Computational Aspects of Carbon and Boron Nanotubes
por: Manuel, Paul
Publicado: (2010)

Synthesis of Boron-Doped Carbon Nanomaterial
por: Chesnokov, Vladimir V., et al.
Publicado: (2023)

Simultaneous construction of two linkages for the on-surface synthesis of imine–boroxine hybrid covalent organic frameworks
por: Yue, Jie-Yu, et al.
Publicado: (2017)

Theoretical investigation of various aspects of two dimensional holey boroxine, B(3)O(3)
por: Ullah, Saif, et al.
Publicado: (2019)

Halogenated boroxine increases propensity to apoptosis in leukemia (UT‐7) but not non‐tumor cells in vitro
por: Hadzic, Maida, et al.
Publicado: (2022)

Self-Healable and Reprocessable Silicon Elastomers Based on Imine–Boroxine Bonds for Flexible Strain Sensor
por: Wang, Peng, et al.
Publicado: (2023)

Thermal Stability and Explosive Hazard Assessment of Diazo Compounds and Diazo Transfer Reagents
por: Green, Sebastian P., et al.
Publicado: (2019)

Integration of enabling methods for the automated flow preparation of piperazine-2-carboxamide
por: Ingham, Richard J, et al.
Publicado: (2014)

Mimicking the surface and prebiotic chemistry of early Earth using flow chemistry
por: Ritson, Dougal J., et al.
Publicado: (2018)

Structural Modification in Carbon Nanotubes by Boron Incorporation
por: Handuja, Sangeeta, et al.
Publicado: (2009)

Modulation of cosmic ray boron and carbon in the heliosphere
por: Potgieter, M S
Publicado: (2005)

Topological analysis of carbon and boron nitride nanotubes
por: Yousaf, Awais, et al.
Publicado: (2020)

Radical Aryl Migration from Boron to Carbon
por: Wang, Dinghai, et al.
Publicado: (2021)

2,4,6-Tris(4-fluorophenyl)-2-(1-pyridyl)-boroxine
por: Pearson, Wayne H., et al.
Publicado: (2007)

Defect-Induced Transport Enhancement in Carbon–Boron Nitride–Carbon Heteronanotube Junctions
por: Algharagholy, Laith A., et al.
Publicado: (2023)

The Diazo-Reaction in Typhoid Fever
por: Friedenwald, Julius
Publicado: (1894)

Formation of Boron-Carbon Nanosheets and Bilayers in Boron-Doped Diamond: Origin of Metallicity and Superconductivity
por: Polyakov, S. N., et al.
Publicado: (2016)

Boron-neutron Capture on Activated Carbon for Hydrogen Storage
por: Romanos, Jimmy, et al.
Publicado: (2019)

Selective Deposition of Hard Boron-Carbon Microstructures on Silicon
por: Samudrala, Gopi, et al.
Publicado: (2021)

Cannot write session to /tmp/vufind_sessions/sess_p36pcbqg5r93v99qn33l1b1prl