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Oxalyl amide assisted palladium-catalyzed synthesis of pyrrolidones via carbonylation of γ-C(sp(3))–H bonds of aliphatic amine substrates

The first Pd-catalyzed regioselective γ-carbonylation of oxalyl amide protected aliphatic amines with carbon monoxide leading to synthesis of pyrrolidones has been developed. Both γ-methyl and cyclopropyl methylene C–H bonds are well activated to obtain the corresponding pyrrolidones in moderate to...

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Detalles Bibliográficos
Autores principales:	Wang, Chao, Zhang, Li, Chen, Changpeng, Han, Jian, Yao, Yingming, Zhao, Yingsheng
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2015
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5861525/ https://www.ncbi.nlm.nih.gov/pubmed/29619163 http://dx.doi.org/10.1039/c5sc00519a

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