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A fluorenylidene-acridane that becomes dark in color upon grinding – ground state mechanochromism by conformational change
We report mechanochromic color change controlled by conformational change (between folded and twisted conformers) of fluorenylidene-acridanes (FAs). FAs with four N-alkyl groups (methyl, ethyl, n-butyl and n-octyl) were synthesized via the Barton–Kellogg reaction of diazofluorene and electrophilic N...
Autores principales: | Suzuki, Tsuyoshi, Okada, Hiroshi, Nakagawa, Takafumi, Komatsu, Kazuki, Fujimoto, Chikako, Kagi, Hiroyuki, Matsuo, Yutaka |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5868075/ https://www.ncbi.nlm.nih.gov/pubmed/29619203 http://dx.doi.org/10.1039/c7sc03567e |
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