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Z-Selective iridium-catalyzed cross-coupling of allylic carbonates and α-diazo esters

A well-defined Ir–allyl complex catalyzes the Z-selective cross-coupling of allyl carbonates with α-aryl diazo esters. The process overrides the large thermodynamic preference for E-products typically observed in metal-mediated coupling reactions to enable the synthesis of Z,E-dieneoates in good yie...

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Detalles Bibliográficos
Autores principales:	Thomas, Bryce N., Moon, Patrick J., Yin, Shengkang, Brown, Alex, Lundgren, Rylan J.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2017
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5869292/ https://www.ncbi.nlm.nih.gov/pubmed/29629093 http://dx.doi.org/10.1039/c7sc04283c

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