Overcoming double-step CO(2) adsorption and minimizing water co-adsorption in bulky diamine-appended variants of Mg(2)(dobpdc)

Alkyldiamine-functionalized variants of the metal–organic framework Mg(2)(dobpdc) (dobpdc(4–) = 4,4′-dioxidobiphenyl-3,3′-dicarboxylate) are promising for CO(2) capture applications owing to their unique step-shaped CO(2) adsorption profiles resulting from the cooperative formation of ammonium carba...

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Detalles Bibliográficos
Autores principales: Milner, Phillip J., Martell, Jeffrey D., Siegelman, Rebecca L., Gygi, David, Weston, Simon C., Long, Jeffrey R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5869309/
https://www.ncbi.nlm.nih.gov/pubmed/29629084
http://dx.doi.org/10.1039/c7sc04266c

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