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Oxygen radical character in group 11 oxygen fluorides

Transition metal complexes bearing terminal oxido ligands are quite common, yet group 11 terminal oxo complexes remain elusive. Here we show that excited coinage metal atoms M (M = Au, Ag, Cu) react with OF(2) to form hypofluorites FOMF and group 11 oxygen metal fluorides OMF(2), OAuF and OAgF. Thes...

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Detalles Bibliográficos
Autores principales:	Li, Lin, Stüker, Tony, Kieninger, Stefanie, Andrae, Dirk, Schlöder, Tobias, Gong, Yu, Andrews, Lester, Beckers, Helmut, Riedel, Sebastian
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group UK 2018
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5871800/ https://www.ncbi.nlm.nih.gov/pubmed/29593258 http://dx.doi.org/10.1038/s41467-018-03630-0

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