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Selective Catalytic Oxidation of Cyclohexene with Molecular Oxygen: Radical Versus Nonradical Pathways

We study the allylic oxidation of cyclohexene with O(2) under mild conditions in the presence of transition‐metal catalysts. The catalysts comprise nanometric metal oxide particles supported on porous N‐doped carbons (M/N:C, M=V, Cr, Fe, Co, Ni, Cu, Nb, Mo, W). Most of these metal oxides give only m...

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Detalles Bibliográficos
Autores principales: Denekamp, Ilse M., Antens, Martijn, Slot, Thierry K., Rothenberg, Gadi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5873426/
https://www.ncbi.nlm.nih.gov/pubmed/29610628
http://dx.doi.org/10.1002/cctc.201701538