Bis(arylimidazole) Iridium Picolinate Emitters and Preferential Dipole Orientation in Films

[Image: see text] The straightforward synthesis and photophysical properties of a new series of heteroleptic iridium(III) bis(2-arylimidazole) picolinate complexes are reported. Each complex has been characterized by nuclear magnetic resonance, UV–vis, cyclic voltammetry, and photoluminescent angle...

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Autores principales: Huckaba, Aron J., Senes, Alessia, Aghazada, Sadig, Babaei, Azin, Meskers, Stefan C. J., Zimmermann, Iwan, Schouwink, Pascal, Gasilova, Natalia, Janssen, René A. J., Bolink, Henk J., Nazeeruddin, Mohammad Khaja
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5879467/
https://www.ncbi.nlm.nih.gov/pubmed/29623303
http://dx.doi.org/10.1021/acsomega.8b00137
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author Huckaba, Aron J.
Senes, Alessia
Aghazada, Sadig
Babaei, Azin
Meskers, Stefan C. J.
Zimmermann, Iwan
Schouwink, Pascal
Gasilova, Natalia
Janssen, René A. J.
Bolink, Henk J.
Nazeeruddin, Mohammad Khaja
author_facet Huckaba, Aron J.
Senes, Alessia
Aghazada, Sadig
Babaei, Azin
Meskers, Stefan C. J.
Zimmermann, Iwan
Schouwink, Pascal
Gasilova, Natalia
Janssen, René A. J.
Bolink, Henk J.
Nazeeruddin, Mohammad Khaja
author_sort Huckaba, Aron J.
collection PubMed
description [Image: see text] The straightforward synthesis and photophysical properties of a new series of heteroleptic iridium(III) bis(2-arylimidazole) picolinate complexes are reported. Each complex has been characterized by nuclear magnetic resonance, UV–vis, cyclic voltammetry, and photoluminescent angle dependency, and the emissive properties of each are described. The preferred orientation of transition dipoles in emitter/host thin films indicated more preferred orientation than homoleptic complex Ir(ppy)(3).
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spelling pubmed-58794672018-04-03 Bis(arylimidazole) Iridium Picolinate Emitters and Preferential Dipole Orientation in Films Huckaba, Aron J. Senes, Alessia Aghazada, Sadig Babaei, Azin Meskers, Stefan C. J. Zimmermann, Iwan Schouwink, Pascal Gasilova, Natalia Janssen, René A. J. Bolink, Henk J. Nazeeruddin, Mohammad Khaja ACS Omega [Image: see text] The straightforward synthesis and photophysical properties of a new series of heteroleptic iridium(III) bis(2-arylimidazole) picolinate complexes are reported. Each complex has been characterized by nuclear magnetic resonance, UV–vis, cyclic voltammetry, and photoluminescent angle dependency, and the emissive properties of each are described. The preferred orientation of transition dipoles in emitter/host thin films indicated more preferred orientation than homoleptic complex Ir(ppy)(3). American Chemical Society 2018-03-06 /pmc/articles/PMC5879467/ /pubmed/29623303 http://dx.doi.org/10.1021/acsomega.8b00137 Text en Copyright © 2018 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Huckaba, Aron J.
Senes, Alessia
Aghazada, Sadig
Babaei, Azin
Meskers, Stefan C. J.
Zimmermann, Iwan
Schouwink, Pascal
Gasilova, Natalia
Janssen, René A. J.
Bolink, Henk J.
Nazeeruddin, Mohammad Khaja
Bis(arylimidazole) Iridium Picolinate Emitters and Preferential Dipole Orientation in Films
title Bis(arylimidazole) Iridium Picolinate Emitters and Preferential Dipole Orientation in Films
title_full Bis(arylimidazole) Iridium Picolinate Emitters and Preferential Dipole Orientation in Films
title_fullStr Bis(arylimidazole) Iridium Picolinate Emitters and Preferential Dipole Orientation in Films
title_full_unstemmed Bis(arylimidazole) Iridium Picolinate Emitters and Preferential Dipole Orientation in Films
title_short Bis(arylimidazole) Iridium Picolinate Emitters and Preferential Dipole Orientation in Films
title_sort bis(arylimidazole) iridium picolinate emitters and preferential dipole orientation in films
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5879467/
https://www.ncbi.nlm.nih.gov/pubmed/29623303
http://dx.doi.org/10.1021/acsomega.8b00137
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