Enantiomeric resolution and X-ray optical activity of a tricobalt extended metal atom chain

A simple procedure based on anion exchange was employed for the enantiomeric resolution of the extended metal atom chain (EMAC) [Co(3)(dpa)(4)(MeCN)(2)](2+). Use of the chiral salt (NBu(4))(2)[As(2)(tartrate)(2)], (Λ-1 or Δ-1), resulted in the selective crystallization of the EMAC enantiomers as [Δ-...

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Detalles Bibliográficos
Autores principales: Srinivasan, Anandi, Cortijo, Miguel, Bulicanu, Vladimir, Naim, Ahmad, Clérac, Rodolphe, Sainctavit, Philippe, Rogalev, Andrei, Wilhelm, Fabrice, Rosa, Patrick, Hillard, Elizabeth A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5884025/
https://www.ncbi.nlm.nih.gov/pubmed/29675158
http://dx.doi.org/10.1039/c7sc04131d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5884025/
https://www.ncbi.nlm.nih.gov/pubmed/29675158
http://dx.doi.org/10.1039/c7sc04131d

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