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Guiding a divergent reaction by photochemical control: bichromatic selective access to levulinates and butenolides

Allylic and acrylic substrates may be efficiently transformed by a sequential bichromatic photochemical process into derivatives of levulinates or butenolides with high selectivity when phenanthrene is used as a regulator. Thus, UV-A photoinduced cross-metathesis (CM) couples the acrylic and allylic...

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Detalles Bibliográficos
Autores principales: Sutar, Revannath L., Sen, Saumik, Eivgi, Or, Segalovich, Gal, Schapiro, Igor, Reany, Ofer, Lemcoff, N. Gabriel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5885942/
https://www.ncbi.nlm.nih.gov/pubmed/29675185
http://dx.doi.org/10.1039/c7sc05094a