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Solvent exchange in preformed photocatalyst-donor precursor complexes determines efficiency

In homogeneous photocatalytic reduction of CO(2), it is widely assumed that the primary electron transfer from the sacrificial donor to the catalyst is diffusion controlled, thus little attention has been paid to optimizing this step. We present spectroscopic evidence that the precursor complex is p...

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Detalles Bibliográficos
Autores principales: Kiefer, Laura M., Kubarych, Kevin J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5887230/
https://www.ncbi.nlm.nih.gov/pubmed/29675196
http://dx.doi.org/10.1039/c7sc04533f