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Solvent exchange in preformed photocatalyst-donor precursor complexes determines efficiency
In homogeneous photocatalytic reduction of CO(2), it is widely assumed that the primary electron transfer from the sacrificial donor to the catalyst is diffusion controlled, thus little attention has been paid to optimizing this step. We present spectroscopic evidence that the precursor complex is p...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5887230/ https://www.ncbi.nlm.nih.gov/pubmed/29675196 http://dx.doi.org/10.1039/c7sc04533f |