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Exploiting exciton coupling of ligand radical intervalence charge transfer transitions to tune NIR absorption

We detail the rational design of a series of bimetallic bis-ligand radical Ni salen complexes in which the relative orientation of the ligand radical chromophores provides a mechanism to tune the energy of intense intervalence charge transfer (IVCT) bands in the near infrared (NIR) region. Through a...

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Detalles Bibliográficos
Autores principales:	Clarke, Ryan M., Jeen, Tiffany, Rigo, Serena, Thompson, John R., Kaake, Loren G., Thomas, Fabrice, Storr, Tim
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2017
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5887452/ https://www.ncbi.nlm.nih.gov/pubmed/29675206 http://dx.doi.org/10.1039/c7sc04537a

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