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A Non‐Heme Iron Photocatalyst for Light‐Driven Aerobic Oxidation of Methanol

Non‐heme (L)Fe(III) and (L)Fe(III)‐O‐Fe(III)(L) complexes (L=1,1‐di(pyridin‐2‐yl)‐N,N‐bis(pyridin‐2‐ylmethyl)ethan‐1‐amine) underwent reduction under irradiation to the Fe(II) state with concomitant oxidation of methanol to methanal, without the need for a secondary photosensitizer. Spectroscopic an...

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Detalles Bibliográficos
Autores principales: Chen, Juan, Stepanovic, Stepan, Draksharapu, Apparao, Gruden, Maja, Browne, Wesley R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5887871/
https://www.ncbi.nlm.nih.gov/pubmed/29334586
http://dx.doi.org/10.1002/anie.201712678

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