Formation of macrocyclic ring systems by carbonylation of trifunctional P/B/B frustrated Lewis pairs

The trifunctional P/B/B frustrated Lewis pairs 11a–c featuring bulky aryl groups at phosphorus [Dmesp (a), Tipp (b), Mes* (c)] react with H(2) by heterolytic hydrogen splitting followed by cleavage of HB(C(6)F(5))(2) to give the zwitterionic six-membered heterocyclic PH phosphonium/borate products 1...

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Detalles Bibliográficos
Autores principales: Wang, Long, Dong, Shunxi, Daniliuc, Constantin G., Liu, Lei, Grimme, Stefan, Knitsch, Robert, Eckert, Hellmut, Hansen, Michael Ryan, Kehr, Gerald, Erker, Gerhard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5890323/
https://www.ncbi.nlm.nih.gov/pubmed/29675199
http://dx.doi.org/10.1039/c7sc04394e

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