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Expansion of the (BB) 〉metallacycle with coinage metal cations: formation of B–M–Ru–B (M = Cu, Ag, Au) dimetalacyclodiboryls

In this work, we introduce a novel approach for the selective assembly of heterometallic complexes by unprecedented coordination of coinage metal cations to strained single ruthenium–boron bonds on a surface of icosahedral boron clusters. M(i) cations (M = Cu, Ag, and Au) insert into B–Ru bonds of t...

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Detalles Bibliográficos
Autores principales:	Eleazer, Bennett J., Smith, Mark D., Popov, Alexey A., Peryshkov, Dmitry V.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2018
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5892348/ https://www.ncbi.nlm.nih.gov/pubmed/29675252 http://dx.doi.org/10.1039/c8sc00190a

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