Understanding light-driven H(2) evolution through the electronic tuning of aminopyridine cobalt complexes

A new family of cobalt complexes with the general formula [Co(II)(OTf)(2)((Y,X)Py(Me)tacn)] (1(R), (Y,X)Py(Me)tacn = 1-[(4-X-3,5-Y-2-pyridyl)methyl]-4,7-dimethyl-1,4,7-triazacyclononane, (X = CN (1(CN)), CO(2)Et (1(CO2Et)), Cl (1(Cl)), H (1(H)), NMe(2) (1(NMe2))) where (Y = H, and X = OMe when Y = M...

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Detalles Bibliográficos
Autores principales: Call, Arnau, Franco, Federico, Kandoth, Noufal, Fernández, Sergio, González-Béjar, María, Pérez-Prieto, Julia, Luis, Josep M., Lloret-Fillol, Julio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5892349/
https://www.ncbi.nlm.nih.gov/pubmed/29675253
http://dx.doi.org/10.1039/c7sc04328g

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