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Direct observation of vibrational energy dispersal via methyl torsions

Explicit evidence for the role of methyl rotor levels in promoting energy dispersal is reported. A set of coupled zero-order vibration/vibration-torsion (vibtor) levels in the S(1) state of para-fluorotoluene (pFT) are investigated. Two-dimensional laser-induced fluorescence (2D-LIF) and two-dimensi...

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Detalles Bibliográficos
Autores principales:	Gardner, Adrian M., Tuttle, William D., Whalley, Laura E., Wright, Timothy G.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2018
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5897844/ https://www.ncbi.nlm.nih.gov/pubmed/29719700 http://dx.doi.org/10.1039/c7sc05309f

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