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Striking transformations of the hydroborylene ligand in a HB:→Ni(II) complex with isocyanides and CO

For the first time, the reactivity of the metal- and N-heterocyclic carbene-supported monovalent hydroborylene is reported. Isocyanides react with the hydroborylene Ni(II) complex [{cat((TMS)L)Si}(Cl)Ni←:BH(NHC)(2)] 1 (cat = ortho-C(6)H(4)O(2); (TMS)L = N(SiMe(3))(Dipp); Dipp = 2,6-Pr(i)(2)C(6)H(3);...

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Detalles Bibliográficos
Autores principales:	Hadlington, T. J., Szilvási, T., Driess, M.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2018
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5897887/ https://www.ncbi.nlm.nih.gov/pubmed/29719715 http://dx.doi.org/10.1039/c7sc04792d

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