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One-pot synthesis of diaryliodonium salts from arenes and aryl iodides with Oxone–sulfuric acid

A facile synthesis of diaryliodonium salts utilizing Oxone as versatile and cheap oxidant has been developed. This method shows wide applicability and can be used for the preparation of iodonium salts containing electron-donating or electron-withdrawing groups in good yields. In addition, this proce...

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Autores principales: Soldatova, Natalia, Postnikov, Pavel, Kukurina, Olga, Zhdankin, Viktor V, Yoshimura, Akira, Wirth, Thomas, Yusubov, Mekhman S
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5905280/
https://www.ncbi.nlm.nih.gov/pubmed/29719579
http://dx.doi.org/10.3762/bjoc.14.70
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author Soldatova, Natalia
Postnikov, Pavel
Kukurina, Olga
Zhdankin, Viktor V
Yoshimura, Akira
Wirth, Thomas
Yusubov, Mekhman S
author_facet Soldatova, Natalia
Postnikov, Pavel
Kukurina, Olga
Zhdankin, Viktor V
Yoshimura, Akira
Wirth, Thomas
Yusubov, Mekhman S
author_sort Soldatova, Natalia
collection PubMed
description A facile synthesis of diaryliodonium salts utilizing Oxone as versatile and cheap oxidant has been developed. This method shows wide applicability and can be used for the preparation of iodonium salts containing electron-donating or electron-withdrawing groups in good yields. In addition, this procedure can be applied to the preparation of symmetric iodonium salts directly from arenes via a one-pot iodination–oxidation sequence.
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spelling pubmed-59052802018-05-01 One-pot synthesis of diaryliodonium salts from arenes and aryl iodides with Oxone–sulfuric acid Soldatova, Natalia Postnikov, Pavel Kukurina, Olga Zhdankin, Viktor V Yoshimura, Akira Wirth, Thomas Yusubov, Mekhman S Beilstein J Org Chem Full Research Paper A facile synthesis of diaryliodonium salts utilizing Oxone as versatile and cheap oxidant has been developed. This method shows wide applicability and can be used for the preparation of iodonium salts containing electron-donating or electron-withdrawing groups in good yields. In addition, this procedure can be applied to the preparation of symmetric iodonium salts directly from arenes via a one-pot iodination–oxidation sequence. Beilstein-Institut 2018-04-12 /pmc/articles/PMC5905280/ /pubmed/29719579 http://dx.doi.org/10.3762/bjoc.14.70 Text en Copyright © 2018, Soldatova et al. https://creativecommons.org/licenses/by/4.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Soldatova, Natalia
Postnikov, Pavel
Kukurina, Olga
Zhdankin, Viktor V
Yoshimura, Akira
Wirth, Thomas
Yusubov, Mekhman S
One-pot synthesis of diaryliodonium salts from arenes and aryl iodides with Oxone–sulfuric acid
title One-pot synthesis of diaryliodonium salts from arenes and aryl iodides with Oxone–sulfuric acid
title_full One-pot synthesis of diaryliodonium salts from arenes and aryl iodides with Oxone–sulfuric acid
title_fullStr One-pot synthesis of diaryliodonium salts from arenes and aryl iodides with Oxone–sulfuric acid
title_full_unstemmed One-pot synthesis of diaryliodonium salts from arenes and aryl iodides with Oxone–sulfuric acid
title_short One-pot synthesis of diaryliodonium salts from arenes and aryl iodides with Oxone–sulfuric acid
title_sort one-pot synthesis of diaryliodonium salts from arenes and aryl iodides with oxone–sulfuric acid
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5905280/
https://www.ncbi.nlm.nih.gov/pubmed/29719579
http://dx.doi.org/10.3762/bjoc.14.70
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