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One-pot synthesis of diaryliodonium salts from arenes and aryl iodides with Oxone–sulfuric acid
A facile synthesis of diaryliodonium salts utilizing Oxone as versatile and cheap oxidant has been developed. This method shows wide applicability and can be used for the preparation of iodonium salts containing electron-donating or electron-withdrawing groups in good yields. In addition, this proce...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5905280/ https://www.ncbi.nlm.nih.gov/pubmed/29719579 http://dx.doi.org/10.3762/bjoc.14.70 |
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author | Soldatova, Natalia Postnikov, Pavel Kukurina, Olga Zhdankin, Viktor V Yoshimura, Akira Wirth, Thomas Yusubov, Mekhman S |
author_facet | Soldatova, Natalia Postnikov, Pavel Kukurina, Olga Zhdankin, Viktor V Yoshimura, Akira Wirth, Thomas Yusubov, Mekhman S |
author_sort | Soldatova, Natalia |
collection | PubMed |
description | A facile synthesis of diaryliodonium salts utilizing Oxone as versatile and cheap oxidant has been developed. This method shows wide applicability and can be used for the preparation of iodonium salts containing electron-donating or electron-withdrawing groups in good yields. In addition, this procedure can be applied to the preparation of symmetric iodonium salts directly from arenes via a one-pot iodination–oxidation sequence. |
format | Online Article Text |
id | pubmed-5905280 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | Beilstein-Institut |
record_format | MEDLINE/PubMed |
spelling | pubmed-59052802018-05-01 One-pot synthesis of diaryliodonium salts from arenes and aryl iodides with Oxone–sulfuric acid Soldatova, Natalia Postnikov, Pavel Kukurina, Olga Zhdankin, Viktor V Yoshimura, Akira Wirth, Thomas Yusubov, Mekhman S Beilstein J Org Chem Full Research Paper A facile synthesis of diaryliodonium salts utilizing Oxone as versatile and cheap oxidant has been developed. This method shows wide applicability and can be used for the preparation of iodonium salts containing electron-donating or electron-withdrawing groups in good yields. In addition, this procedure can be applied to the preparation of symmetric iodonium salts directly from arenes via a one-pot iodination–oxidation sequence. Beilstein-Institut 2018-04-12 /pmc/articles/PMC5905280/ /pubmed/29719579 http://dx.doi.org/10.3762/bjoc.14.70 Text en Copyright © 2018, Soldatova et al. https://creativecommons.org/licenses/by/4.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms) |
spellingShingle | Full Research Paper Soldatova, Natalia Postnikov, Pavel Kukurina, Olga Zhdankin, Viktor V Yoshimura, Akira Wirth, Thomas Yusubov, Mekhman S One-pot synthesis of diaryliodonium salts from arenes and aryl iodides with Oxone–sulfuric acid |
title | One-pot synthesis of diaryliodonium salts from arenes and aryl iodides with Oxone–sulfuric acid |
title_full | One-pot synthesis of diaryliodonium salts from arenes and aryl iodides with Oxone–sulfuric acid |
title_fullStr | One-pot synthesis of diaryliodonium salts from arenes and aryl iodides with Oxone–sulfuric acid |
title_full_unstemmed | One-pot synthesis of diaryliodonium salts from arenes and aryl iodides with Oxone–sulfuric acid |
title_short | One-pot synthesis of diaryliodonium salts from arenes and aryl iodides with Oxone–sulfuric acid |
title_sort | one-pot synthesis of diaryliodonium salts from arenes and aryl iodides with oxone–sulfuric acid |
topic | Full Research Paper |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5905280/ https://www.ncbi.nlm.nih.gov/pubmed/29719579 http://dx.doi.org/10.3762/bjoc.14.70 |
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