Cobalt-catalyzed directed C–H alkenylation of pivalophenone N–H imine with alkenyl phosphates

A cobalt–N-heterocyclic carbene (NHC) catalyst efficiently promotes an ortho C–H alkenylation reaction of pivalophenone N–H imine with an alkenyl phosphate. The reaction tolerates various substituted pivalophenone N–H imines as well as cyclic and acyclic alkenyl phosphates.

Detalles Bibliográficos
Autores principales: Xu, Wengang, Yoshikai, Naohiko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2018
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5905286/
https://www.ncbi.nlm.nih.gov/pubmed/29719569
http://dx.doi.org/10.3762/bjoc.14.60
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author Xu, Wengang
Yoshikai, Naohiko
author_facet Xu, Wengang
Yoshikai, Naohiko
author_sort Xu, Wengang
collection PubMed
description A cobalt–N-heterocyclic carbene (NHC) catalyst efficiently promotes an ortho C–H alkenylation reaction of pivalophenone N–H imine with an alkenyl phosphate. The reaction tolerates various substituted pivalophenone N–H imines as well as cyclic and acyclic alkenyl phosphates.
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spelling pubmed-59052862018-05-01 Cobalt-catalyzed directed C–H alkenylation of pivalophenone N–H imine with alkenyl phosphates Xu, Wengang Yoshikai, Naohiko Beilstein J Org Chem Full Research Paper A cobalt–N-heterocyclic carbene (NHC) catalyst efficiently promotes an ortho C–H alkenylation reaction of pivalophenone N–H imine with an alkenyl phosphate. The reaction tolerates various substituted pivalophenone N–H imines as well as cyclic and acyclic alkenyl phosphates. Beilstein-Institut 2018-03-28 /pmc/articles/PMC5905286/ /pubmed/29719569 http://dx.doi.org/10.3762/bjoc.14.60 Text en Copyright © 2018, Xu and Yoshikai https://creativecommons.org/licenses/by/4.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Xu, Wengang
Yoshikai, Naohiko
Cobalt-catalyzed directed C–H alkenylation of pivalophenone N–H imine with alkenyl phosphates
title Cobalt-catalyzed directed C–H alkenylation of pivalophenone N–H imine with alkenyl phosphates
title_full Cobalt-catalyzed directed C–H alkenylation of pivalophenone N–H imine with alkenyl phosphates
title_fullStr Cobalt-catalyzed directed C–H alkenylation of pivalophenone N–H imine with alkenyl phosphates
title_full_unstemmed Cobalt-catalyzed directed C–H alkenylation of pivalophenone N–H imine with alkenyl phosphates
title_short Cobalt-catalyzed directed C–H alkenylation of pivalophenone N–H imine with alkenyl phosphates
title_sort cobalt-catalyzed directed c–h alkenylation of pivalophenone n–h imine with alkenyl phosphates
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5905286/
https://www.ncbi.nlm.nih.gov/pubmed/29719569
http://dx.doi.org/10.3762/bjoc.14.60
work_keys_str_mv AT xuwengang cobaltcatalyzeddirectedchalkenylationofpivalophenonenhiminewithalkenylphosphates
AT yoshikainaohiko cobaltcatalyzeddirectedchalkenylationofpivalophenonenhiminewithalkenylphosphates

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