A highly stable and hierarchical tetrathiafulvalene-based metal–organic framework with improved performance as a solid catalyst

Herein we report the synthesis of a tetrathiafulvalene (TTF)-based MOF, namely MUV-2, which shows a non-interpenetrated hierarchical crystal structure with mesoporous one-dimensional channels of ca. 3 nm and orthogonal microporous channels of ca. 1 nm. This highly stable MOF (aqueous solution with p...

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Detalles Bibliográficos
Autores principales: Souto, Manuel, Santiago-Portillo, Andrea, Palomino, Miguel, Vitórica-Yrezábal, Iñigo J., Vieira, Bruno J. C., Waerenborgh, João C., Valencia, Susana, Navalón, Sergio, Rey, Fernando, García, Hermenegildo, Mínguez Espallargas, Guillermo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5909329/
https://www.ncbi.nlm.nih.gov/pubmed/29732116
http://dx.doi.org/10.1039/c7sc04829g
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author Souto, Manuel
Santiago-Portillo, Andrea
Palomino, Miguel
Vitórica-Yrezábal, Iñigo J.
Vieira, Bruno J. C.
Waerenborgh, João C.
Valencia, Susana
Navalón, Sergio
Rey, Fernando
García, Hermenegildo
Mínguez Espallargas, Guillermo
author_facet Souto, Manuel
Santiago-Portillo, Andrea
Palomino, Miguel
Vitórica-Yrezábal, Iñigo J.
Vieira, Bruno J. C.
Waerenborgh, João C.
Valencia, Susana
Navalón, Sergio
Rey, Fernando
García, Hermenegildo
Mínguez Espallargas, Guillermo
author_sort Souto, Manuel
collection PubMed
description Herein we report the synthesis of a tetrathiafulvalene (TTF)-based MOF, namely MUV-2, which shows a non-interpenetrated hierarchical crystal structure with mesoporous one-dimensional channels of ca. 3 nm and orthogonal microporous channels of ca. 1 nm. This highly stable MOF (aqueous solution with pH values ranging from 2 to 11 and different organic solvents), which possesses the well-known [Fe(3)(μ(3)-O)(COO)(6)] secondary building unit, has proven to be an efficient catalyst for the aerobic oxidation of dibenzothiophenes.
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spelling pubmed-59093292018-05-04 A highly stable and hierarchical tetrathiafulvalene-based metal–organic framework with improved performance as a solid catalyst Souto, Manuel Santiago-Portillo, Andrea Palomino, Miguel Vitórica-Yrezábal, Iñigo J. Vieira, Bruno J. C. Waerenborgh, João C. Valencia, Susana Navalón, Sergio Rey, Fernando García, Hermenegildo Mínguez Espallargas, Guillermo Chem Sci Chemistry Herein we report the synthesis of a tetrathiafulvalene (TTF)-based MOF, namely MUV-2, which shows a non-interpenetrated hierarchical crystal structure with mesoporous one-dimensional channels of ca. 3 nm and orthogonal microporous channels of ca. 1 nm. This highly stable MOF (aqueous solution with pH values ranging from 2 to 11 and different organic solvents), which possesses the well-known [Fe(3)(μ(3)-O)(COO)(6)] secondary building unit, has proven to be an efficient catalyst for the aerobic oxidation of dibenzothiophenes. Royal Society of Chemistry 2018-01-24 /pmc/articles/PMC5909329/ /pubmed/29732116 http://dx.doi.org/10.1039/c7sc04829g Text en This journal is © The Royal Society of Chemistry 2018 https://creativecommons.org/licenses/by/3.0/This article is freely available. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (CC BY 3.0)
spellingShingle Chemistry
Souto, Manuel
Santiago-Portillo, Andrea
Palomino, Miguel
Vitórica-Yrezábal, Iñigo J.
Vieira, Bruno J. C.
Waerenborgh, João C.
Valencia, Susana
Navalón, Sergio
Rey, Fernando
García, Hermenegildo
Mínguez Espallargas, Guillermo
A highly stable and hierarchical tetrathiafulvalene-based metal–organic framework with improved performance as a solid catalyst
title A highly stable and hierarchical tetrathiafulvalene-based metal–organic framework with improved performance as a solid catalyst
title_full A highly stable and hierarchical tetrathiafulvalene-based metal–organic framework with improved performance as a solid catalyst
title_fullStr A highly stable and hierarchical tetrathiafulvalene-based metal–organic framework with improved performance as a solid catalyst
title_full_unstemmed A highly stable and hierarchical tetrathiafulvalene-based metal–organic framework with improved performance as a solid catalyst
title_short A highly stable and hierarchical tetrathiafulvalene-based metal–organic framework with improved performance as a solid catalyst
title_sort highly stable and hierarchical tetrathiafulvalene-based metal–organic framework with improved performance as a solid catalyst
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5909329/
https://www.ncbi.nlm.nih.gov/pubmed/29732116
http://dx.doi.org/10.1039/c7sc04829g
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