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Incorporation of redox-inactive cations promotes iron catalyzed aerobic C–H oxidation at mild potentials
The synthesis and characterization of the Schiff base complexes Fe(ii) (2M) and Fe(iii)Cl (3M), where M is a K(+) or Ba(2+) ion incorporated into the ligand, are reported. The Fe(iii/ii) redox potentials are positively shifted by 440 mV (2K) and 640 mV (2Ba) compared to Fe(salen) (salen = N,N′-bis(s...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5911827/ https://www.ncbi.nlm.nih.gov/pubmed/29732136 http://dx.doi.org/10.1039/c7sc04486k |