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Carbon Cloth Supported Nano-Mg(OH)(2) for the Enrichment and Recovery of Rare Earth Element Eu(III) From Aqueous Solution
Nano-Mg(OH)(2) is attracting great attention as adsorbent for pre-concentration and recovery of rare earth elements (REEs) from low-concentration solution, due to its superior removal efficiency for REEs and environmental friendliness. However, the nanoparticles also cause some severe problems durin...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Frontiers Media S.A.
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5915470/ https://www.ncbi.nlm.nih.gov/pubmed/29721492 http://dx.doi.org/10.3389/fchem.2018.00118 |
Sumario: | Nano-Mg(OH)(2) is attracting great attention as adsorbent for pre-concentration and recovery of rare earth elements (REEs) from low-concentration solution, due to its superior removal efficiency for REEs and environmental friendliness. However, the nanoparticles also cause some severe problems during application, including aggregation, blockage in fixed-bed column, as well as the difficulties in separation and reuse. Herein, in order to avoid the mentioned problems, a carbon cloth (CC) supported nano-Mg(OH)(2) (nano-Mg(OH)(2)@CC) was synthesized by electrodeposition. The X-ray diffraction and scanning electron microscopy analysis demonstrated that the interlaced nano-sheet of Mg(OH)(2) grew firmly and uniformly on the surface of carbon cloth fibers. Batch adsorption experiments of Eu(III) indicated that the nano-Mg(OH)(2)@CC composite maintained the excellent adsorption performance of nano-Mg(OH)(2) toward Eu(III). After adsorption, the Eu containing composite was calcined under nitrogen atmosphere. The content of Eu(2)O(3) in the calcined material was as high as 99.66%. Fixed-bed column experiments indicated that no blockage for Mg(OH)(2)@CC composite was observed during the treatment, while the complete blockage of occurred to nano-Mg(OH)(2) at an effluent volume of 240 mL. Moreover, the removal efficiency of Mg(OH)(2)@CC was still higher than 90% until 4,200 mL of effluent volume. This work provides a promising method for feasible application of nanoadsorbents in fixed-bed process to recycle low-concentration REEs from wastewater. |
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