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Tailored trisubstituted chiral Cp(x)Rh(III) catalysts for kinetic resolutions of phosphinic amides
A trisubstituted chiral Cp(x) ligand family is introduced. Based on the disubstituted atropchiral Cp(x) ligand scaffold, the introduction of a bulky third substituent at the central position of the Cp ring leads to substantially increased selectivities for rhodium(iii)-catalyzed kinetic resolutions...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5915793/ https://www.ncbi.nlm.nih.gov/pubmed/29732080 http://dx.doi.org/10.1039/c7sc05411d |