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Benchmarking lithium amide versus amine bonding by charge density and energy decomposition analysis arguments
Lithium amides are versatile C–H metallation reagents with vast industrial demand because of their high basicity combined with their weak nucleophilicity, and they are applied in kilotons worldwide annually. The nuclearity of lithium amides, however, modifies and steers reactivity, region- and stere...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5916014/ https://www.ncbi.nlm.nih.gov/pubmed/29732094 http://dx.doi.org/10.1039/c7sc05368a |