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Benchmarking lithium amide versus amine bonding by charge density and energy decomposition analysis arguments

Lithium amides are versatile C–H metallation reagents with vast industrial demand because of their high basicity combined with their weak nucleophilicity, and they are applied in kilotons worldwide annually. The nuclearity of lithium amides, however, modifies and steers reactivity, region- and stere...

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Detalles Bibliográficos
Autores principales:	Engelhardt, Felix, Maaß, Christian, Andrada, Diego M., Herbst-Irmer, Regine, Stalke, Dietmar
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2018
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5916014/ https://www.ncbi.nlm.nih.gov/pubmed/29732094 http://dx.doi.org/10.1039/c7sc05368a

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