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Uranyl Sulfate Nanotubules Templated by N-phenylglycine
The synthesis, structure, and infrared spectroscopy properties of the new organically templated uranyl sulfate Na(phgH(+))(7)[(UO(2))(6)(SO(4))(10)](H(2)O)(3.5) (1), obtained at room temperature by evaporation from aqueous solution, are reported. Its structure contains unique uranyl sulfate [(UO(2))...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5923546/ https://www.ncbi.nlm.nih.gov/pubmed/29614011 http://dx.doi.org/10.3390/nano8040216 |
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author | Siidra, Oleg I. Nazarchuk, Evgeny V. Charkin, Dmitry O. Chukanov, Nikita V. Depmeier, Wulf Bocharov, Sergey N. Sharikov, Mikhail I. |
author_facet | Siidra, Oleg I. Nazarchuk, Evgeny V. Charkin, Dmitry O. Chukanov, Nikita V. Depmeier, Wulf Bocharov, Sergey N. Sharikov, Mikhail I. |
author_sort | Siidra, Oleg I. |
collection | PubMed |
description | The synthesis, structure, and infrared spectroscopy properties of the new organically templated uranyl sulfate Na(phgH(+))(7)[(UO(2))(6)(SO(4))(10)](H(2)O)(3.5) (1), obtained at room temperature by evaporation from aqueous solution, are reported. Its structure contains unique uranyl sulfate [(UO(2))(6)(SO(4))(10)](8−) nanotubules templated by protonated N-phenylglycine (C(6)H(5)NH(2)CH(2)COOH)(+). Their internal diameter is 1.4 nm. Each of the nanotubules is built from uranyl sulfate rings sharing common SO(4) tetrahedra. The template plays an important role in the formation of the complex structure of 1. The aromatic rings are stacked parallel to each other due to the effect of π–π interaction with their side chains extending into the gaps between the nanotubules. |
format | Online Article Text |
id | pubmed-5923546 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-59235462018-05-03 Uranyl Sulfate Nanotubules Templated by N-phenylglycine Siidra, Oleg I. Nazarchuk, Evgeny V. Charkin, Dmitry O. Chukanov, Nikita V. Depmeier, Wulf Bocharov, Sergey N. Sharikov, Mikhail I. Nanomaterials (Basel) Article The synthesis, structure, and infrared spectroscopy properties of the new organically templated uranyl sulfate Na(phgH(+))(7)[(UO(2))(6)(SO(4))(10)](H(2)O)(3.5) (1), obtained at room temperature by evaporation from aqueous solution, are reported. Its structure contains unique uranyl sulfate [(UO(2))(6)(SO(4))(10)](8−) nanotubules templated by protonated N-phenylglycine (C(6)H(5)NH(2)CH(2)COOH)(+). Their internal diameter is 1.4 nm. Each of the nanotubules is built from uranyl sulfate rings sharing common SO(4) tetrahedra. The template plays an important role in the formation of the complex structure of 1. The aromatic rings are stacked parallel to each other due to the effect of π–π interaction with their side chains extending into the gaps between the nanotubules. MDPI 2018-04-03 /pmc/articles/PMC5923546/ /pubmed/29614011 http://dx.doi.org/10.3390/nano8040216 Text en © 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Siidra, Oleg I. Nazarchuk, Evgeny V. Charkin, Dmitry O. Chukanov, Nikita V. Depmeier, Wulf Bocharov, Sergey N. Sharikov, Mikhail I. Uranyl Sulfate Nanotubules Templated by N-phenylglycine |
title | Uranyl Sulfate Nanotubules Templated by N-phenylglycine |
title_full | Uranyl Sulfate Nanotubules Templated by N-phenylglycine |
title_fullStr | Uranyl Sulfate Nanotubules Templated by N-phenylglycine |
title_full_unstemmed | Uranyl Sulfate Nanotubules Templated by N-phenylglycine |
title_short | Uranyl Sulfate Nanotubules Templated by N-phenylglycine |
title_sort | uranyl sulfate nanotubules templated by n-phenylglycine |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5923546/ https://www.ncbi.nlm.nih.gov/pubmed/29614011 http://dx.doi.org/10.3390/nano8040216 |
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