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Humate-assisted Synthesis of MoS(2)/C Nanocomposites via Co-Precipitation/Calcination Route for High Performance Lithium Ion Batteries

A facile, cost-effective, non-toxic, and surfactant-free route has been developed to synthesize MoS(2)/carbon (MoS(2)/C) nanocomposites. Potassium humate consists of a wide variety of oxygen-containing functional groups, which is considered as promising candidates for functionalization of graphene....

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Autores principales: Geng, Qin, Tong, Xin, Wenya, Gideon Evans, Yang, Chao, Wang, Jide, Maloletnev, A. S., Wang, Zhiming M., Su, Xintai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer US 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5924512/
https://www.ncbi.nlm.nih.gov/pubmed/29704073
http://dx.doi.org/10.1186/s11671-018-2537-y
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author Geng, Qin
Tong, Xin
Wenya, Gideon Evans
Yang, Chao
Wang, Jide
Maloletnev, A. S.
Wang, Zhiming M.
Su, Xintai
author_facet Geng, Qin
Tong, Xin
Wenya, Gideon Evans
Yang, Chao
Wang, Jide
Maloletnev, A. S.
Wang, Zhiming M.
Su, Xintai
author_sort Geng, Qin
collection PubMed
description A facile, cost-effective, non-toxic, and surfactant-free route has been developed to synthesize MoS(2)/carbon (MoS(2)/C) nanocomposites. Potassium humate consists of a wide variety of oxygen-containing functional groups, which is considered as promising candidates for functionalization of graphene. Using potassium humate as carbon source, two-dimensional MoS(2)/C nanosheets with irregular shape were synthesized via a stabilized co-precipitation/calcination process. Electrochemical performance of the samples as an anode of lithium ion battery was measured, demonstrating that the MoS(2)/C nanocomposite calcinated at 700 °C (MoS(2)/C-700) electrode showed outstanding performance with a high discharge capacity of 554.9 mAh g(− 1) at a current density of 100 mA g(− 1) and the Coulomb efficiency of the sample maintained a high level of approximately 100% after the first 3 cycles. Simultaneously, the MoS(2)/C-700 electrode exhibited good cycling stability and rate performance. The success in synthesizing MoS(2)/C nanocomposites via co-precipitation/calcination route may pave a new way to realize promising anode materials for high-performance lithium ion batteries. ELECTRONIC SUPPLEMENTARY MATERIAL: The online version of this article (10.1186/s11671-018-2537-y) contains supplementary material, which is available to authorized users.
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spelling pubmed-59245122018-05-03 Humate-assisted Synthesis of MoS(2)/C Nanocomposites via Co-Precipitation/Calcination Route for High Performance Lithium Ion Batteries Geng, Qin Tong, Xin Wenya, Gideon Evans Yang, Chao Wang, Jide Maloletnev, A. S. Wang, Zhiming M. Su, Xintai Nanoscale Res Lett Nano Express A facile, cost-effective, non-toxic, and surfactant-free route has been developed to synthesize MoS(2)/carbon (MoS(2)/C) nanocomposites. Potassium humate consists of a wide variety of oxygen-containing functional groups, which is considered as promising candidates for functionalization of graphene. Using potassium humate as carbon source, two-dimensional MoS(2)/C nanosheets with irregular shape were synthesized via a stabilized co-precipitation/calcination process. Electrochemical performance of the samples as an anode of lithium ion battery was measured, demonstrating that the MoS(2)/C nanocomposite calcinated at 700 °C (MoS(2)/C-700) electrode showed outstanding performance with a high discharge capacity of 554.9 mAh g(− 1) at a current density of 100 mA g(− 1) and the Coulomb efficiency of the sample maintained a high level of approximately 100% after the first 3 cycles. Simultaneously, the MoS(2)/C-700 electrode exhibited good cycling stability and rate performance. The success in synthesizing MoS(2)/C nanocomposites via co-precipitation/calcination route may pave a new way to realize promising anode materials for high-performance lithium ion batteries. ELECTRONIC SUPPLEMENTARY MATERIAL: The online version of this article (10.1186/s11671-018-2537-y) contains supplementary material, which is available to authorized users. Springer US 2018-04-27 /pmc/articles/PMC5924512/ /pubmed/29704073 http://dx.doi.org/10.1186/s11671-018-2537-y Text en © The Author(s). 2018 Open AccessThis article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.
spellingShingle Nano Express
Geng, Qin
Tong, Xin
Wenya, Gideon Evans
Yang, Chao
Wang, Jide
Maloletnev, A. S.
Wang, Zhiming M.
Su, Xintai
Humate-assisted Synthesis of MoS(2)/C Nanocomposites via Co-Precipitation/Calcination Route for High Performance Lithium Ion Batteries
title Humate-assisted Synthesis of MoS(2)/C Nanocomposites via Co-Precipitation/Calcination Route for High Performance Lithium Ion Batteries
title_full Humate-assisted Synthesis of MoS(2)/C Nanocomposites via Co-Precipitation/Calcination Route for High Performance Lithium Ion Batteries
title_fullStr Humate-assisted Synthesis of MoS(2)/C Nanocomposites via Co-Precipitation/Calcination Route for High Performance Lithium Ion Batteries
title_full_unstemmed Humate-assisted Synthesis of MoS(2)/C Nanocomposites via Co-Precipitation/Calcination Route for High Performance Lithium Ion Batteries
title_short Humate-assisted Synthesis of MoS(2)/C Nanocomposites via Co-Precipitation/Calcination Route for High Performance Lithium Ion Batteries
title_sort humate-assisted synthesis of mos(2)/c nanocomposites via co-precipitation/calcination route for high performance lithium ion batteries
topic Nano Express
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5924512/
https://www.ncbi.nlm.nih.gov/pubmed/29704073
http://dx.doi.org/10.1186/s11671-018-2537-y
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