Persulfate Reaction in a Hair‐Bleaching Formula: Unveiling the Unconventional Reactivity of 1,13‐Diamino‐4,7,10‐Trioxatridecane

The stability and unconventional reactivity of 1,13‐diamino‐4,7,10‐trioxatridecane in the presence of NH(3), H(2)O(2), and (NH(4))(2)S(2)O(8) are described. The ether‐diamine is an ingredient marketed to hair salons and consumers for so‐called “plex” services to compensate for hair damage during ble...

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Autores principales: Gargano, Emanuele M., Mangiatordi, Giuseppe F., Weber, Ingo, Goebel, Carsten, Alberga, Domenico, Nicolotti, Orazio, Ruess, Wolfgang, Wierlacher, Stefan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5931532/
https://www.ncbi.nlm.nih.gov/pubmed/29744283
http://dx.doi.org/10.1002/open.201800013
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author Gargano, Emanuele M.
Mangiatordi, Giuseppe F.
Weber, Ingo
Goebel, Carsten
Alberga, Domenico
Nicolotti, Orazio
Ruess, Wolfgang
Wierlacher, Stefan
author_facet Gargano, Emanuele M.
Mangiatordi, Giuseppe F.
Weber, Ingo
Goebel, Carsten
Alberga, Domenico
Nicolotti, Orazio
Ruess, Wolfgang
Wierlacher, Stefan
author_sort Gargano, Emanuele M.
collection PubMed
description The stability and unconventional reactivity of 1,13‐diamino‐4,7,10‐trioxatridecane in the presence of NH(3), H(2)O(2), and (NH(4))(2)S(2)O(8) are described. The ether‐diamine is an ingredient marketed to hair salons and consumers for so‐called “plex” services to compensate for hair damage during bleaching. The main reaction product identified is an unexpected azanyl ester derivative. This is considered relevant for the safety evaluation when used in cosmetic products. The mechanism of reaction was explored through DFT calculations. This study represents the first attempt to assess the stability of a plex active in an oxidative environment.
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spelling pubmed-59315322018-05-09 Persulfate Reaction in a Hair‐Bleaching Formula: Unveiling the Unconventional Reactivity of 1,13‐Diamino‐4,7,10‐Trioxatridecane Gargano, Emanuele M. Mangiatordi, Giuseppe F. Weber, Ingo Goebel, Carsten Alberga, Domenico Nicolotti, Orazio Ruess, Wolfgang Wierlacher, Stefan ChemistryOpen Communications The stability and unconventional reactivity of 1,13‐diamino‐4,7,10‐trioxatridecane in the presence of NH(3), H(2)O(2), and (NH(4))(2)S(2)O(8) are described. The ether‐diamine is an ingredient marketed to hair salons and consumers for so‐called “plex” services to compensate for hair damage during bleaching. The main reaction product identified is an unexpected azanyl ester derivative. This is considered relevant for the safety evaluation when used in cosmetic products. The mechanism of reaction was explored through DFT calculations. This study represents the first attempt to assess the stability of a plex active in an oxidative environment. John Wiley and Sons Inc. 2018-03-25 /pmc/articles/PMC5931532/ /pubmed/29744283 http://dx.doi.org/10.1002/open.201800013 Text en © 2018 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Communications
Gargano, Emanuele M.
Mangiatordi, Giuseppe F.
Weber, Ingo
Goebel, Carsten
Alberga, Domenico
Nicolotti, Orazio
Ruess, Wolfgang
Wierlacher, Stefan
Persulfate Reaction in a Hair‐Bleaching Formula: Unveiling the Unconventional Reactivity of 1,13‐Diamino‐4,7,10‐Trioxatridecane
title Persulfate Reaction in a Hair‐Bleaching Formula: Unveiling the Unconventional Reactivity of 1,13‐Diamino‐4,7,10‐Trioxatridecane
title_full Persulfate Reaction in a Hair‐Bleaching Formula: Unveiling the Unconventional Reactivity of 1,13‐Diamino‐4,7,10‐Trioxatridecane
title_fullStr Persulfate Reaction in a Hair‐Bleaching Formula: Unveiling the Unconventional Reactivity of 1,13‐Diamino‐4,7,10‐Trioxatridecane
title_full_unstemmed Persulfate Reaction in a Hair‐Bleaching Formula: Unveiling the Unconventional Reactivity of 1,13‐Diamino‐4,7,10‐Trioxatridecane
title_short Persulfate Reaction in a Hair‐Bleaching Formula: Unveiling the Unconventional Reactivity of 1,13‐Diamino‐4,7,10‐Trioxatridecane
title_sort persulfate reaction in a hair‐bleaching formula: unveiling the unconventional reactivity of 1,13‐diamino‐4,7,10‐trioxatridecane
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5931532/
https://www.ncbi.nlm.nih.gov/pubmed/29744283
http://dx.doi.org/10.1002/open.201800013
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