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Discovery of moganite in a lunar meteorite as a trace of H(2)O ice in the Moon’s regolith

Moganite, a monoclinic SiO(2) phase, has been discovered in a lunar meteorite. Silica micrograins occur as nanocrystalline aggregates of mostly moganite and occasionally coesite and stishovite in the KREEP (high potassium, rare-earth element, and phosphorus)–like gabbroic-basaltic breccia NWA 2727,...

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Detalles Bibliográficos
Autores principales: Kayama, Masahiro, Tomioka, Naotaka, Ohtani, Eiji, Seto, Yusuke, Nagaoka, Hiroshi, Götze, Jens, Miyake, Akira, Ozawa, Shin, Sekine, Toshimori, Miyahara, Masaaki, Tomeoka, Kazushige, Matsumoto, Megumi, Shoda, Naoki, Hirao, Naohisa, Kobayashi, Takamichi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Association for the Advancement of Science 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5931767/
https://www.ncbi.nlm.nih.gov/pubmed/29732406
http://dx.doi.org/10.1126/sciadv.aar4378
Descripción
Sumario:Moganite, a monoclinic SiO(2) phase, has been discovered in a lunar meteorite. Silica micrograins occur as nanocrystalline aggregates of mostly moganite and occasionally coesite and stishovite in the KREEP (high potassium, rare-earth element, and phosphorus)–like gabbroic-basaltic breccia NWA 2727, although these grains are seemingly absent in other lunar meteorites. We interpret the origin of these grains as follows: alkaline water delivery to the Moon via carbonaceous chondrite collisions, fluid capture during impact-induced brecciation, moganite precipitation from the captured H(2)O at pH 9.5 to 10.5 and 363 to 399 K on the sunlit surface, and meteorite launch from the Moon caused by an impact at 8 to 22 GPa and >673 K. On the subsurface, this captured H(2)O may still remain as ice at estimated bulk content of >0.6 weight %. This indicates the possibility of the presence of abundant available water resources underneath local sites of the host bodies within the Procellarum KREEP and South Pole Aitken terranes.